Enhancing Heat Treatment Learning for Mechanical Engineering Students: A Comparative Study of Corrosion Inhibitor Effectiveness on Aluminium Protection
Abstract
Corrosion still remains a serious problem in the application of aluminum alloys, such as Aluminum 6061, which is one of the most widely used aluminum alloys in industries because of its high strength-to-weight ratio. However, the material degrades when exposed to aggressive environments, such as acidic, alkaline, or salty solutions, and the control of corrosion has been achieved with the use of synthetic chemical inhibitors, but the increasing concern of environmental and health risks has shifted attention to more eco-friendly alternatives. The present study aimed at evaluating the efficacy of three vegetable oils (coconut oil, palm oil, and soybean oil) as environmentally friendly corrosion inhibitors for Aluminum 6061, and the alloy coupons were subjected to three different corrosive solutions (hydrochloric acid, sodium hydroxide, and sodium chloride). A quantitative experimental procedure was employed to determine the corrosion rate through the measurement of the weight loss of aluminum coupons prior to and after the immersion, and the results showed that all three oils were able to reduce the corrosion rate when compared to the samples without any inhibitor. Among them, coconut oil gave the best protection, followed by soybean oil and palm oil, because the adsorption of the organic compounds and fatty acids in the oils onto the aluminum surface formed a thin layer that separated the metal and the corrosive environment. Consequently, the results also showed that the use of bio-based oils can be a promising alternative to synthetic corrosion inhibitors in industries that use aluminumbased materials.
Downloads
References
Al-Otaibi, M. S., Al-Mayouf, A. M., Khan, M., Mousa, A. A., Al-Mazroa, S. A., & Alkhathlan, H. Z. (2014). Corrosion inhibitory action of some plant extracts on the corrosion of mild steel in acidic media. Arabian Journal of Chemistry, 7(3), 340–346. https://doi.org/10.1016/j.arabjc.2012.01.015
Bierwagen, G., Tallman, D., Li, J., He, L., & Jeffcoate, C. (2003). EIS studies of coated metals in accelerated exposure. Progress in organic coatings, 46(2), 149–158.
Deshpande, V., & Jyothi, P. (2022). A review on sustainable eco-friendly cutting fluids. Journal of Sustainability and Environmental Management, 1(2), 306–320.
El-Etre, A. (2003). Inhibition of aluminum corrosion using Opuntia extract. Corrosion science, 45(11), 2485–2495.
El-Lateef, H. M. A., El-Dabea, T., Khalaf, M. M., & Abu-Dief, A. M. (2022). Innovation of imine metal chelates as corrosion inhibitors at different media: A collective study. International Journal of Molecular Sciences, 23(16), 9360.
Galleguillos Madrid, F. M., Soliz, A., Cáceres, L., Bergendahl, M., Leiva-Guajardo, S., Portillo, C., Olivares, D., Toro, N., Jimenez-Arevalo, V., & Páez, M. (2024). Green Corrosion Inhibitors for Metal and Alloys Protection in Contact with Aqueous Saline. Materials, 17(16), 3996.
Iroha, N. B., & Maduelosi, N. J. (2021). Corrosion inhibitive action and adsorption behaviour of justicia secunda leaves extract as an eco-friendly inhibitor for aluminium in acidic media. Biointerface Res. Appl. Chem, 11, 13019–13030.
Kazeem, R. A., Fadare, D. A., Ikumapayi, O. M., Adediran, A. A., Aliyu, S. J., Akinlabi, S. A., Jen, T.-C., & Akinlabi, E. T. (2022). Advances in the application of vegetable-oil-based cutting fluids to sustainable machining operations—A review. Lubricants, 10(4), 69.
Negm, N. A., El-Farargy, A. F., Abdel Halim, E. A., El-lboudy, S., & Ahmed, A. E.-S. I. (2014). Novel biobased nonionic surfactants: Synthesis, surface activity and corrosion inhibition efficiency against aluminum alloy dissolution in acidic media. Journal of surfactants and detergents, 17, 1203–1211.
Njoku, D. I., Ukaga, I., Ikenna, O. B., Oguzie, E. E., Oguzie, K. L., & Ibisi, N. (2016). Natural products for materials protection: Corrosion protection of aluminium in hydrochloric acid by Kola nitida extract. Journal of Molecular Liquids, 219, 417–424.
Popoola, L. T., Grema, A. S., Latinwo, G. K., Gutti, B., & Balogun, A. S. (2013). Corrosion problems during oil and gas production and its mitigation. International Journal of Industrial Chemistry, 4, 1–15.
Raja, P. B., & Sethuraman, M. G. (2008). Natural products as corrosion inhibitor for metals in corrosive media—A review. Materials letters, 62(1), 113–116.
Rajimol, P., Ulaeto, S. B., Puthiyamadam, A., Sahoo, S. K., Rajan, T., Radhakrishnan, K., & Sukumaran, R. K. (2023). Development of an oxyresveratrol incorporated bio-based smart nanocomposite coating with anti-corrosive, self-healing, and anti-microbial properties. Green Chemistry, 25(18), 7189–7215.
Shwethambika, P., & Ishwara Bhat, J. (2021). Matured Theobroma Cocoa Pod Extracts as Green Inhibitor for Acid Corrosion of Aluminium. Iranian Journal of Chemistry and Chemical Engineering, 40(3), 906–919.
Verma, C., Haque, J., Quraishi, M., & Ebenso, E. E. (2019). Aqueous phase environmental friendly organic corrosion inhibitors derived from one step multicomponent reactions: A review. Journal of Molecular Liquids, 275, 18–40.
Wickramasinghe, K., Sasahara, H., Abd Rahim, E., & Perera, G. (2021). Recent advances on high performance machining of aerospace materials and composites using vegetable oil-based metal working fluids. Journal of Cleaner Production, 310, 127459.
Copyright (c) 2025 Saifuddin Karim (Author)

This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.







